DETERMINATION OF CHLORIDE CONTENT IN BOTTLED MINERAL WATER
DOI:
https://doi.org/10.7251/ASB220301003BKeywords:
mineral waters, chlorides, Mohr’s method, standard addition method, method confirmationAbstract
Mineral waters from different sources have different contents, because each source has its own individual physical and chemical characteristics. Chlorides appear in natural waters because of the dissolution of minerals from sediments, but also because of anthropogenic influence. In this paper, Mohr's method of chloride content determination was used. Natural mineral waters “aqua viva” and “ELEMENT” were used for testing. Determination by Mohr’s method was performed in water samples without the addition of standard and with the addition of standard, as well as in the standards themselves. In water samples without the addition of standards, much higher chloride content values were obtained than those given by the declaration. The results of the Recovery test obtained after the determination of chloride content in the samples with the addition of the standard confirmed the applied method for the used concentration range. Based on the difference in the chloride content in the samples with the addition of standard and the standards themselves, the values of the chloride content in the sample were determined and they were closer to the values stated on the declaration. Given the results of the performed analyses, it can be concluded that they are in agreement with literature data, i.e. Mohr’s method is more suitable for determination in samples with high chloride concentrations. In samples containing low concentrations of chloride, a tendency towards increased results was recorded, which was also the case in this research.
References
Bekić, A. (2019). Spektrofotometrijsko i kromatografsko određivanje aniona i kationa u uzorcima konzumne vode [Graduate thesis]. Sveučilište Josipa Jurja Strossmayera u Osijeku, Odjel za kemiju, Osijek.
Bitar, F. (2016). Determination of Chloride Ion Concentration in Drinking Water of Al Hawash Area. Research Journal of Pharmacy and Technology, 9(6), 701-710. doi:10.5958/0974-360X.2016.00133.5
Blagojević, D. (2007). Promjena kvaliteta mineralnih voda Guber-Srebrenica pod različitim uslovima ambalažiranja i skladištenja [Master' thesis]. Univerzitet u Banjoj Luci, Tehnološki fakultet, Banja Luka.
Blagojević, D. (2021). Gravimetrijske i volumetrijske metode analize, Praktikum sa teorijskim osnovama. Banja Luka: Univerzitet u Banjoj Luci, Prirodno-matematički fakultet.
Bratovcic, A. & Odobasic, A. (2011). Determination Fluoride and Chloride Contents in Drinking Water by Ion Selective Electrode. In E. Ekundayo (Ed.), Environmental Monitoring (pp. 109-120). IntechOpen. doi:10.5772/27223
Bulgariu, L., Robu, B., Bilba, D. & Macoveanu, M. (2007). Analyses by Conductometric Titration of Chlorides from Wastewaters that Contains Heavy Metals. Annals of West University of Timisoara, Series Chemistry, 16(1), 1-8.
Burns, D. C., Danzer, K. & Townshend, K. (2002). Use of the terms ,,recovery" and ,,apparent recovery" in analytical procedures (IUPAC Recommendations). Pure and Applied Chemistry, 74(11), 2201-2205.
Coll, H. (1957). Spectrophotometric Determination of Chloride Ion. LSU Historical Dissertations and Theses. 197, Louisiana: Louisiana State University and Agricultural & Mechanical College.
Đuković, J., Đukić, B., Lazić, D., & Marsenić, M. (2000). Tehnologija vode. Zvornik: Univerzitet u Istočnom Sarajevu, Tehnološki fakultet.
Flueraru, L., Raul, G., Tataru, M. & Bulgariu, L. (2014). Analysis Methods of Chloride Ions with Industrial Applications. Buletinul Institutului Polytehnic din Iasi, LX (LXIV)(2), 45-56.
Hunt, M., Herron, E. & Green, L. (2012). Chlorides in Fresh Water. URI Watershed Watch, 4, 1-4.
Iacoban, C. & Macoveanu, M. (2005). A Comparation of Argentometric Titration and Spectrophotometric Determination of Chloride Concentration in Precipitation Samples. Romanian Biotechnological Letters, 10(2), 2105-2109.
Kelly, W. R., Panno, S. V. & Hackley, K. (2012). The Sources, Distribution, and Trends of Chloride in the Waters of Illinois. Bulletin B-74. Champain, Illinois: Illinois State Water Survey, Prairie Research Institute, University of Illinois at Urbana-Champaign.
Laketić, T. J., Pavlović, A. N., Savić, M. J., Mitić, S. S., Tošić, S. B. & Miljković, M. N. (2014). Sadržaj anjona u podzemnim vodama na teritoriji Semberije. Savremene tehnologije, 3(1), 38-46.
Matijević, B. (2013). Kontrola kvaliteta i validacija analitičkih metoda, primena u volumetrijskoj i gravimetrijskoj analizi. Novi Sad: Univerzitet u Novom Sadu, Prirodno-matematički fakultet, Departman za hemiju, biohemiju i zaštitu životne sredine.
Maya, F., Estela, J. M. & Cerda, V. (2008). Spectrophotometric determination of chloride in waters using a multisyringe flow injection system. Talanta, 74, 1534-1538.
Mesquita, R. B., Fernandes, S. M. & Rangel, A. O. (2002). Turbidimetric determination of chloride in different types of water using a single sequential injection analysis system. Journal of Environmental Monitoring, 4(3), 458-461. doi:10.1039/b200456a
Official Gazette of the Republic of Srpska, No. 75 (2015). Pravilnik o zdravstvenoj ispravnosti vode za piće.
Rajković, M. B., Mitrović, M. & Antić-Mladenović, S. (2019). Obezbeđenje poverenja u kvalitet rezultata hemijskih metoda ispitivanja. Zaštita materijala, 60(4), 342-359.
Shukla, M. & Arya, S. (2018). Determination of Chloride Ion Concentration in Ganga River Water by Mohr Method at Kanpur. Green Chemistry & Tecnology Letters, 4(1), 6-8. doi:10.18510/gctl.2018.412
Sladojević, S. (2016). Analitička hemija: Kvantitativna hemijska analiza: Teorijske osnove, praktikum, računski primjeri. Banja Luka: Univerzitet u Banjoj Luci, Tehnološki fakultet.
Thomas, J. F. (1954). Mercurimetric Determination of Chloride. American Water Works Association, 46(3), 257-262. doi:10.1002/j.1551-8833.1954.tb16052.x
Videnović, J. (2018). Komparativna analiza kvaliteta voda za vodosnabdevanje grada Niša i flaširanih voda u prometu [Master' thesis].Univerzitet u Nišu, Fakultet zaštite na radu, Niš.
Vindakijević, J. & Sladojević, S. (2005). Analitička hemija, Kvantitativna hemijska analiza, Teorijske osnove klasičnih metoda analize. Banja Luka: Univerzitet u Banjoj Luci, Tehnološki fakultet.
Vučijak, B., Ćerić, A., Silajdžić, I. & Kurtagić, S. M. (2011). Voda za život: Osnove integralnog upravljanja vodnim resursima. Sarajevo: Institut za hidrotehniku Građevinskog fakulteta u Sarajevu.
Wu, D., Hu, Y., Liu, Y. & Zhang, R. (2021). Review of Chloride Ion Detection Technology in Water. Applied Sciences, 11, 11137. doi:10.3390/app112311137